Constructing Free Standing Metal Organic Framework MIL-53 Membrane Based on Anodized Aluminum Oxide Precursor
نویسندگان
چکیده
منابع مشابه
Constructing Free Standing Metal Organic Framework MIL-53 Membrane Based on Anodized Aluminum Oxide Precursor
Metal organic framework (MOF) materials have attracted great attention due to their well-ordered and controllable pores possessing of prominent potentials for gas molecule sorption and separation performances. Organizing the MOF crystals to a continuous membrane with a certain scale will better exhibit their prominent potentials. Reports in recent years concentrate on well grown MOF membranes o...
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MIL-53-Cu has been synthesized hydrothermally and has been used for the first time for gas separation. MIL-53-Cu shows adsorption capacities of 8.1, 0.7 and 0.5 m.mol/g, respectively, for CH4, CO2 and H2 at 30 bar and 298 K. The high CH4 adsorption capacity of MIL-53-Cu maybe attributed to the high pore volume and large number of open metal sites....
متن کاملWater Adsorption in Flexible Gallium-Based MIL-53 Metal−Organic Framework
Understanding the adsorption of water in metal−organic frameworks (MOF), and particularly in soft porous crystals, is a crucial prerequisite before considering MOFs for industrial applications. We report here a joint experimental and theoretical study on the behavior of a gallium-based breathing MOF, Ga-MIL-53, upon water adsorption. By looking at the energetics and thermodynamics of Ga-MIL-53,...
متن کاملsynthesis of nanoporous metal organic framework mil-53-cu and its application for gas separation
mil-53-cu has been synthesized hydrothermally and has been used for the first time for gas separation. mil-53-cu shows adsorption capacities of 8.1, 0.7 and 0.5 m.mol/g, respectively, for ch4, co2 and h2 at 30 bar and 298 k. the high ch4 adsorption capacity of mil-53-cu maybe attributed to the high pore volume and large number of open metal sites. the high selectivity for ch4 over co2 (11.5) an...
متن کاملComplex adsorption of short linear alkanes in the flexible metal-organic-framework MIL-53(Fe).
This investigation is based on a combination of experimental tools completed by a computational approach to deeply characterize the unusual adsorption behavior of the flexible MIL-53(Fe) in the presence of short linear alkanes. In contrast to the aluminum or chromium analogues we previously reported, the iron MIL-53 solid, which initially exhibits a closed structure in the dry state, shows more...
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ژورنال
عنوان ژورنال: Scientific Reports
سال: 2014
ISSN: 2045-2322
DOI: 10.1038/srep04947